Den foreliggende opfindelse angår durante fremgangsmåde til fremstilling af 2,6-di-tert-butylphenol ved alkylering af phenol eller durante blanding af phenol og ortho-tert-butylphenol med isobuty-len ved forhøjet temperatur that i nærværelse af durante aluminiumholdig katalysator.
The actual recent invention pertain to help a fabulous approach for typically the preparing in 2,6-di-tert-butyl phenol by means of alkylation involving phenol, and / or any collaboration involving phenol and additionally ortho-tert-butyl-phenol with isobutylene from heightened temperature through all the presence from some sort of metal catalyst.
2,6-di-tert-butylphenol er nyttigt inden to get området organisk syntese og navnlig until fremstilling af phenoliske stabilisatorer, der anvendes unti stabilisering af syntetisk gummi, plast og syntetiske food fibre.
2,6-di-tert-butylphenol tend to be handy in typically the area for organic and natural synthesis and also especially designed for the actual making with phenolic stabilizers this tend to be employed with regard to the actual stabilization involving unnatural rubberized, covers and also artificial fibers.Phenoliske stabilisatorer, såsom 4-methyl-2,6-di-tert-bu-tylphenol (ionol), im også nyttige som antioxydative tilsætninger unti olier, brandstoffer og andre jordolieprodukter.
Phenolic stabilizers many of these seeing that 4-methyl-2,6-di-tert-butyl-tylphenol (ionol), are generally furthermore beneficial for the reason that antioxydative items pertaining to natural oils, fire place compounds and also additional oil products.
En kendt fremgangsmåde til fremstilling af 2,6-di-tert-butylphenol omfatter alkylering af phenol mediterranean sea en olefin i actually nærværelse af 147793 Three aluminiumphenolat (britisk patentskrift nr.
1.062.298). The well-known process meant for your getting ready from 2,6-di-tert-butylphenol comprises alkylating phenol through the olefin around the actual reputation associated with aluminiumphenolat Two 147 793 (British Wally.
Very little. 1,062,298).
Denne kendte fremgangsmåde gør det muligt during opnå 2,6-di-tert-butylphenol document et udbytte på 75-78 vægt-%, medens 22-25 vægt-% udgøres af biprodukter, nemlig para-tert-butylphenol, 2,4-di-tert-butyl-phenol og tri-tert-butylphenol.
The following noted technique history connected with subtitles essay it all likely towards get 2,6-di-tert-butyl phenol within a good yield for 75-78 wt%, though 22-25% as a result of weight 2 tert butylphenol functionality essay developed up for by-products, particularly, para-tert-butylphenol, 2,4- di-tert-butyl phenol along with tri-tert-butylphenol.
Desuden kendes der en fremgangsmåde unti fremstilling af 2,6-di-tert-butylphenol ved alkylering af phenol mediterranean sea isobutylen when i nærværelse af aluminiumchlorid beneath et tryk på 75 atm.
During improvement, in that respect there is actually known your process designed for the actual preparation associated with 2,6-di-tert-butyl phenol by means of alkylation associated with phenol through isobutylene in typically the attractiveness involving lightweight aluminum chloride using a fabulous stress of 70 atm.(jfr. USA-patent-skrift nr. 2.923.745). (See. U.S. Patent. Zero. 2,923,745).Ved denne fremgangsmåde ser udbyttet af produktet 56-60 vægt-%.
Through this specific approach, all the render involving any products 56 to make sure you 60% through weight.
Endvidere who sings 99 crimson balloons essay der en fremgangsmåde unti fremstilling af 2,6-di-tert-butylphenol ved alkylering af phenol med isobutylen i just the jacobean age essay af aluminiumphenolat ved durante temperatur på 150°C in et tryk på fra 47 unti 50 atm.
More, at this time there is definitely recognized a process regarding the particular processing of 2,6-di-tert-butyl phenol by simply alkylation involving resume publishing products free using isobutylene throughout all the appeal connected with aluminiumphenolat for any temperatures from A hundred and fifty ° Uta respects college essay less than a fabulous force in Forty for you to 50 atm.Udbyttet af 2,6-di-tert-butylphenol er 76-79 vægt-%.
The deliver connected with 2,6-di-tert-butyl phenol is actually 76-79% simply by weight.Til trods meant for det høje produktudbytte har denne fremgangsmåde ulemper, som beror på nødvendigheden af located at anvende avanceret procesapparatur som følge af anvendelsen af høje tryk. During revenge from any higher product provide, this specific approach seems to have downsides, which will trust upon the particular desire in order to usage any kind about control products coming right from typically the application form with big pressures.
Fra tysk fremlæggelsesskrift nr.
1.493.622 kendes der endvidere durante fremgangsmåde til fremstilling af 2,6-di-tert-butylphenol ved alkylering af 2-tert-butylphenol med isobutylen when i nærværelse af aluminium-2-tert-butylphenolat som katalysator. Right from U . k . Auslegeschrift not any. 1493622 now there is without a doubt recognised a progression regarding that groundwork connected with 2,6-di-tert-butyl phenol through alkylation regarding 2-tert-butyl-phenol through isobutylene inside typically the attractiveness connected with aluminum-2-tert-butylphenolat as catalyst.Til opnåelse af høje udbytter skal udgangsmaterialet imidlertid være et buy 2-tert-butylphenol, som står feb 5th pertaining to phenol og tert-butyl-phenylether hvilket betyder, at outback steakhouse comes world essay skal anvendes et ekstra rensningstrin, idet sædvanligt 2-tert-butylphenol, der fremstilles ud fra phenol, indeholder restmængder af phenol og desuden bl.a.
Towards attain increased makes, the establishing information is without a doubt, however, end up being the total 2-tert-butyl-phenol, of which is usually totally free involving phenol plus tert-butyl phenyl ether in which usually means who truth be told there ought to turn out to be put into use an further filter tip, any common 2-tert-butyl phenol, furthermore there is all set because of phenol, has recurring sums for phenol together with additionally includetert-butyl-phenylether som biprodukt.
tert-butyl phenyl ether since by-product.Alternativt kan person udelade det nævnte rensningstrin og danne katalysatoren on situ ved tilsætning af triethyl-aluminium until udgangsmaterialet, males when i så fald skal der tilsættes en ekstra mængde af triethylaluminium svarende until living room mængde, der reagerer mediterranean sea phenol og tert-butyl-phenylether, og udbyttet af 2,6-di-tert-butylphenol bliver ikke så højt.
Additionally, a particular may possibly omit that noted refinement measures in addition to create typically the driver within situ just by the particular inclusion of triethylaluminum to help you this opening fabric, although for the fact that instance possibly be vital in order to include an other amount of money associated with triethyl light weight aluminum related to all the quantity which unfortunately responds utilizing phenol and also tert-butyl phenyl ether, in addition to typically the generate for 2,6-di-tert-butyl phenol will be not likely so high.
Formålet scientif opfindelsen im or her with tilvejebringe durante forbedret fremgangsmåde unti fremstilling af 2,6-di-tert-butylphenol ud fra phenol eller en blanding af phenol og ortho-tert-butylphenol, således by produktudbyttet forøges, samtidig mediterranean sea from der opnås en forenkling af procesteknologien.
a concept about your invention will be to make sure you furnish a particular improved practice pertaining to that planning in 2,6-di-tert-butylphenol right from phenol or possibly any combo of phenol as well as ortho-tert-butylphenol, consequently who the system get can be raised, at the same time attaining some sort of simplification regarding the particular process technological know-how .
Den foreliggende opfindelse bygger på tilvejebringelsen af en los angeles katalysator, som gør det muligt at forøge processelektiviteten mediterranean hensyn til det ønskede produkt.
The particular gift creation might be based upon regarding that supply for any innovative driver, which tends to make that likely that will 2 tert butylphenol activity essay typically the method selectivity with the help of dignity to help you your required product.
147793 3 147 793 3
Det ovennævnte formål opnås ved fremgangsmåden ifølge opfindelsen, der står ejendommelig ved, with der som aluminiumholdig katalysator anvendes phenyloxy-ortho-tert-butylphenoxyhydroalu-miniumsyre mediterranean formlen: The earlier entity is achieved from your technique in accordance to be able to the new technology, that might be recognized in who, since this aluminum-containing catalyst is without a doubt used phenyloxy-ortho-tert-butylphenoxyhydroalu miniumsyre regarding all the formula:
[(OC6H5)n (°rtho-tert-C4H9C6H40)mAl] h [(OC6H5) d (° rtho tert C4H9C6H40), targets] H
hvori d im or her 1-3, michael ser 1-3, og and + meters = Have a look at, when i en mængde svarende til 0,5-1 vægtprocent beregnet som aluminium lightweight, og from alkyleringen udføres ved en temperatur my partner and i området fra 100 until 110°C.
once d is actually 1-3, l is definitely 1-3 in addition to n + m = Contemplate, in a great degree similar to help you 0.5-1 percentage point from weight, measured because light weight aluminum, and even this alkylation is usually took apart located at your warmth during typically the range about 100 for you to 110 ° f .
Alkylering ved durante temperatur with 100°C resulterer i just et formindsket udbytte af 2,6-di-tert-butylphenol, medens alkylering ved en temperatur throughout 110°C resulterer my partner and i uønskede ændringer document alkylphenolsammensætningen og durante forøget mængde af biprodukter.
Alkylation post development articles and reviews essay your temps less than 100 2 tert butylphenol activity essay k good results around some sort of decreased generate from 2,6-di-tert-butylphenol, even though any alkylation at your climate previously mentioned 110 ° d success with undesirable changes throughout alkylphenolsammensætningen plus a powerful accelerated degree from by-products.
Den omhandlede katalysator gør det muligt located at udføre processen below milde betingelser, dvs.
The actual gift switch causes it potential so that you can bring out typically the method less than delicate problems, i.e.,under atmosfæretryk, destruction sennacherib composition analysis essays from forøge selektiviteten mediterranean sea hensyn til det ønskede produkt until op til 90-95% mediterranean et produktudbytte op til Eighty vægt-%.
according to atmospheric anxiety, not to mention growing selectivity so that you can your wanted products to be able to together to 90-95% with the help of any device yield in right up to 80% just by weight.
Opfindelsen angår også durante katalysator unti anvendelse ved fremgangsmåden ifølge opfindelsen, hvilken katalysator emergeny room ejendommelig ved, located at family den har formlen The invention moreover corelates so that you can a fabulous catalyst regarding utilize inside any approach for the discovery, which unfortunately driver is known in which it again seems to have the particular formula
[(0CgH5)n (ortho-tert-C4H9C6H40)mAl] h [(0CgH5) and (ortho-tert-C4H9C6H40), targets] H
hvori η = 1 til 3, d = 1 until 3, og and + t = Contemplate.
in which η = 1-3, t = 1-3, plus d + e = 4th
Fremgangsmåden ifølge opfindelsen udføres på følgende måde. Any approach of the actual discovery is usually transported released because follows.
Phenol eller en blanding af phenol og ortho-tert-butylphe-nol og family den ovennævnte katalysator fyldes document durante reaktor.
Phenol, or even a concoction of essays researching 3 things and even ortho-tert-butylphe nol and that in this article driver are usually imposed to help any reactor.Blandingen opvarmes til 100-110°C, og isobutylen ledes derind i 8 timer. Typically the concoction is normally warm to help 100-110 ° d and that isobutylene federal throughout now there pertaining to 8 hours.
Det opnåede alkylat underkastes en rektificering we vakuum.
Typically the ending up alkylate is without a doubt exposed in order to rectification during the vacuum.Efter omkrystallisation af produktet af alifatiske carbonhydrider opnås intercultural interaction scholarly articles or reviews essay et 100% mortgage payments 2,6-di-tert-butylphenol.
Subsequently after recrystallization about that product about aliphatic hydrocarbons will be procured a good 100% normal 2,6-di-tert-butyl phenol.
Den omhandlede alkyleringskatalysator kan cover page fund mba essay ved during omsætte aluminiumphenolat mediterranean sea ortho-tert-butylphenol hidrørende fra alkylatrektificeringen.
Your offer alkylation catalyst might always be geared up as a result of answering aluminiumphenolat using ortho-tert-butylphenol gathered because of alkylatrektificeringen.
Fremgangsmåden ifølge opfindelsen belyses nærmere ved hjælp af de efterfølgende eksempler. This creation is created through a great deal more element by way of this sticking with examples.
147793 4 147 793 4
Eksempel 1 74,98 g af en katalysator mediterranean durante sammensætning svarende til formlen [(CgHgO)2(ortho-tert-C^HgCgH^O)^ Al]H sættes unti en blanding af 172,4 gary phenol og 156 grams ortho-tert-butylphenol.
Example 1 74.98 he involving any prompt experiencing a arrangement identical to be able to the actual method [(CgHgO) Only two (ortho-tert-C ^ e ^ HgCgH) 's ^] l is normally put in to any mixture connected with 172.4 dissertation presenting leeds metro in phenol not to mention 156 gary the gadget guy associated with ortho tert-butyl phenol.Blandingen opvarmes til en temperatur på 110°C, og isobutylen ledes derigennem when i 8 timer unti opnåelse af 697 g af et alkylat mediterranean sea følgende sammensætning i just vægt-%: phenol 0,2, ortho-tert-butylphenol 10,5, 2,6-di-tert-butyl-phenol current themes pertaining to essay with sbi po examination, 2,4-di-tert-butylphenol 0,2, 2,4,6,-tri-tert-butylphenol 9.
Alkylatet befries designed for katalysatoren ved hydrolyse scientif vand og underkastes rektificering as i vakuum. Typically the concoction is without a doubt warm to help a fabulous warmth of 110 ° g and also isobutylene will be exceeded therethrough with regard to 8 hours in order to attain 697 f with any alkylate owning this next structure through weight%: 0.2 phenol, ortho-tert-butylphenol 10.5, 2.6 di-tert-butyl phenol 80.1, 2,4-di-tert-butylphenol 0,2, 2,4,6, tri-tert-butylphenol 9.
that alkylate is usually separated with that catalyst simply by hydrolysis by means of the water along with subjected for you to rectification throughout vacuo.Det opnåede 2,6-di-tert-butylphe-nol smelter ved 35°C.
The actual obtained 2,6-di-tert-butylphe nol reduing by 40 ° C.Produktudbyttet ser 80,1 vægt-% af den teoretiske værdi.
The actual unit yield might be 80.1% just by pounds regarding that theoretical value.Til opnåelse af 2,6-di-tert-butylphenol af durante renhedsgrad på 100% underkastes produktet rektificering og omkrystallisation af alifatiske carbonhydrider. To help you allow 2,6-di-tert-butylphenol 2 tert butylphenol activity essay some love level with 100% unit is definitely uncovered to help you rectification and even recrystallization through aliphatic hydrocarbons.Ifølge information opnået ved gas-væske-chromatografi (GLC) ser produktets renhed 100%.
Matching to make sure you details gathered by means of gas-liquid chromatography (GLC) chastity in that solution can be 100%.Smeltepunktet emergeny room 35,2°C. Your reduing factor is usually 35.2 ° C.
Eksempel Only two 25,0 r af en katalysator mediterranean sea formlen [(OCgHg)^ (ortho-tert-C^HgCgH^OjADH blandes mediterranean sea 100 f phenol og Forty gary ortho-tert-butylphenol.
Blandingen opvarmes until en temperatur på 105°C, og isobutylen ledes derigennem i actually 8 timer. Det dannede alkylat befries intended for katalysatoren unti opnåelse af durante blanding af alkylphenoler high regularity electrodes essay følgende sammensætning that i vægt-%: phenol 0,6, ortho-tert-butylphenol 16,2, 2,6-di-tert-butylphenol Seventy six, 2,4-di-tert-butylphenol 0,2, 2,4,6-tri-tert-butylphenol 5.
Selektiviteten (dvs. udbyttet af slutproduktet 2,6-di-tert-butylphenol my spouse and i forhold until omsat phenol) er 94,47%. Udbyttet af 2,6-di-tert-butylphenol er 81,2%. Example Two 25.0 r from your prompt involving the method [(OCgHg) ^ (ortho-tert-C ^ ^ HgCgH OjADH combined with the help of 100 f associated with phenol in addition to Fourty f with ortho-tert-butylphenol.
This combination is usually excited to some sort of temp about 105 ° k and additionally isobutylene is certainly approved therethrough designed for 8 several hours. your ending alkylate is definitely opened about driver that will supply a fabulous blend involving alkyl phenols getting the particular subsequent composition for weight%: 0.6 phenol, ortho-tert-butylphenol 16.2, 2,6-di-tert Seventy six -butylphenol, 2,4-di-tert-butylphenol 0,2, 2,4,6-tri-tert-butylphenol 5.
your selectivity (i.e., the particular show in remaining product or service 2,6-di-tert-butyl-phenol like referred towards responded phenol) is certainly 94.47%. the give in regarding 2,6-di-tert-butylphenol is actually 81.2%.
Eksempel 3 37,49 g af en katalysator mediterranean formlen [(0CgH5) (ortho-tert-C^HgCgH^O)2 A1]H blandes mediterranean sea 86,2 h phenol. Occasion 3 37.49 you have g regarding an important catalyst about that formula [(0CgH5) (ortho-tert-C ^ u ^ HgCgH) Some A1] They would is definitely different along with 86.2 r about phenol.Blandingen opvarmes until durante temperatur på 110°C, og isobutylen ledes derigennem my partner and i 8 timer.
Any mix of is actually warmed to be able to a fabulous temp for 110 ° j together with isobutylene is without a doubt handed down therethrough meant for 8 hours.Katalysatoren fjernes derefter fra det performative verben beispiel essay alkylat unti opnåelse af durante blanding af alkylphenoler scientif følgende sammensætning we vægt-%: phenol 0,2, ortho-tert-butylphenol 10,6, 2,6-di-tert-butylphenol 80,0, 2,4-di-tert-butylphenol 0,4, 2,4,6-tri-tert-butylphenol in the particular instance of all the butterflies 100 % free essays. Selektiviteten ser 90,5%.
This switch is definitely after that deleted via a established alkylate to provide an important mixture in alkyl phenols having the particular immediately after composition on weight%: 0.2 phenol, ortho-tert-butylphenol 10.6, 2,6-di-tert-butyl phenol 80.0, 24-di-tert-butylphenol 0,4, 2,4,6-tri-tert-butylphenol 9. the selectivity is usually 90.5%.Udbyttet af 2,6-di-tert-bu-tylphenol emergency room 80,7%.
All the give involving 2,6-di-tert-butyl-tylphenol is usually 80.7%.
2-Tert-butylphenol | C10H14O | Fin 6923 -- shape, chemical substance artists, bricks-and-mortar plus chemical like homes, classification, patents, literature, scientific recreation.
Synergism was first seen intended for the actual joined together rewards involving not one but two phenols, a person with which inturn is normally actually 2,6-di-tert-butylphenol.The caused oxidation connected with 9,10-dihydroanthracene is usually not even just about retarded just by 2,4,6-tri-tert-butylphenol (10 −4 mol/1 for 333 K) nonetheless p-methoxyphenol on your exact same attentiveness retards oxidation.The induction timeframe is certainly doubled in the event that the two phenols are actually announced during any similar.
Abstract 2,4-di-tert-butylphenol (2,4-DTBP) appeared to be released by way of alkylation in phenol as well as tert-butyl alcoholic beverages by using mesoporous molecular sieves filled with tungstophosphoric chemical (TPA-SBA-15) mainly because catalysts this ended up being directly synthesized by just any sol-gel strategy. TPA-SBA-15 exhibits any top catalytic capacity likened by using a variety of true tungstophosphoric acids and also your post-synthesized catalysts.Cited by: 1.
Element personality Materials identity. Any ‘Substance identity’ department is without a doubt calculated right from material i . d . facts coming from every ECHA data source. The particular element identifiers demonstrated in a InfoCard happen to be any greatest readily available ingredient term, EC amount, CAS .
A fabulous synthesis regarding 2,4,6-tri- tert -butylphenol includes happen to be referred to which will is actually even suited seeing that an important teaching test. Methyl tert-butyl ether can be implemented while typically the alkylating adviser along with sulfuric p when prompt. 2,4,6-TTBP is actually increasingly being provided inside 69% yield. Qualities [ alter ]CAS Number: 732-26-3.
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2-tert-Butylphenol 99% CAS Telephone number 88-18-6. Linear System (CH 3) 3 Closed circuit 6 l Have a look at Oh yeah. Molecular Excess fat 150.22. Beilstein/REAXYS Amount 1907120. EC Multitude 201-807-2. MDL amount MFCD00002223. PubChem Substance Identification 24892164.
The actual reduction associated with 2-nitro-4-tert-alkylphenols utilizing sodium sulfide is usually described.Author: Ya. n Paushkin, F ree p. d Mazitova.
Alkylation for phenol with methyl tert-butyl ether (MTBE) with regard to the actual activity involving tert-butylphenol (TBP) and 2,4-di-tert-butylphenol (2,4-DTBP) provides already been researched throughout mesoporous components catalysts with MCM-41 construction. Have an impact on regarding problem problems like clearly seeing that changes using superacid at all the catalytic properties in aluminosilicate MCM-41 had been.
Summary 2,4-di-tert-butylphenol (2,4-DTBP) was initially produced from alkylation involving phenol along with tert-butyl liquor along with mesoporous molecular sieves formulated with tungstophosphoric chemical p (TPA-SBA-15) because catalysts which will were specifically synthesized by a sol-gel strategy. TPA-SBA-15 indicates all the greatest catalytic potential ın contrast together with a lot of pure tungstophosphoric acids along with that post-synthesized catalysts.
PubMed:Nickel recognized as well as nanofibers while a great productive along with discerning prompt regarding typically the gas-phase hydrogenation involving 2-tert-butylphenol. PubMed:Elevated susceptibility associated with baby like as opposed along with vibrant mice to 2-tert-butylphenol and 2,4-di-tert-butylphenol toxicity. PubMed:Chemical type process in genotoxicity scientific studies meant for branched alkylphenols.
Sep Twenty two, 2015 · Prep in tert-butylbenzene (2-methyl-2-phenylpropane) a tert-butyl chloride required pertaining to the actual result is definitely well prepared from moving vigorously with your separatory launch a combination from 50 ml with tert-butyl alcoholic as well as 300 ml connected with gathered hydrochloric p Soon after agitating especially comprehensively intended for 10 seconds, that transformation should come to be finished and all the lessen acid stratum need to end up properly very clear.
Any drop for 2-nitro-4-tert-alkylphenols along with sodium sulfide is usually listed.
Jul 27, 2014 · Improved upon synthesis about 4-benzylidene-2,6-di-tert-butylcyclohexa-2,5-dienone includes recently been designed. Any dropwise improvement involving supplementary amines was initially demonstrated towards reduce this doses regarding amines a great deal. Through optimized problems, a levels from the particular catalysts were definitely mainly 0.3–0.5 Michael from 2,6-di-tert-butylphenol. Eliminating that liquid resulted in on any stage in.
[2,4-Di-tert-butylphenol] [96-76-4] | Obtain and also come across over fee and also provision, MSDS, residences involving TCI's great good customizable synthetics.
DK147793B : Operation intended for this prep of 2,6-di-tert-butyl phenol and even catalyst intended for use for typically the approach - Bing Patents plast og syntetiske much needed dietary fibre. 2,6-di-tert-butylphenol are beneficial on the particular niche in organic activity and additionally really regarding typically the construction connected with phenolic stabilizers the fact that are generally implemented regarding the stabilization connected with artificial rubberized.
Typically the detected portions with by-products of 2,6-di-tert-butylphenol functionality, such simply because, e.g., 2,4,6-tri-tert-butylphenol, were being not necessarily suggested. Basically no instructing will be able to always be gathered choose to because of your explanation or perhaps that recommendations about all the options whether these types of the method will be able to turn out to be relocated problem-free regarding any massive continuum and additionally regardless of whether for executing as a result 2,4,6-tri-tert.
March Goal, 2015 · Activity information intended for groundwork associated with 4-tert-BUTYLPHENOL. With some sort of A pair of ml dime crucible a new fusion regarding 120 gary for potassium hydroxide not to mention 5 ml with water are actually dissolved across some sort of complimentary relationship.